Solvent Recovery
Recycling and recovery of solvents is an important downstream issue that should be considered. Solvent recovery can have a positive effect on the environmental impact and hence the metrics of a given process. Studies have been carried out to determine whether solvent recovery is viable depending upon factors such as the energy required to achieve this.[1] ETH Zurich has also developed an LCA-based tool that quantifies the environmental impact of waste-solvent treatment.
The incineration of spent solvents, as opposed to their recovery, has been shown to considerably increase life cycle impacts.[2] However, this depends on the complexity of the production of the solvent itself and its boiling point; for solvents such as diethyl ether, incineration is a preferable option than distillation in terms of Total Cumulative Energy Demand (CED).[3]
Where solvent recovery is deemed to be uneconomical, other options include downcycling the solvent for example for heat recovery or use in other industrial applications.[4]
Other approaches could include solvent ‘leasing’ whereby used solvent is collected by supplier and cleaned up for reuse.
- M. J. Raymond, S. C. Slater and M. J. Savelski, LCA approach to the analysis of solvent waste issues in the pharmaceutical industry, Green Chem., 2010, 12, 1826-1834.
- C. Jiménez-González, A. D. Curzons, D. J. C. Constable and V. L. Cunningham, Cradle-to-gate life cycle inventory and assessment of pharmaceutical compounds, Int. J. LCA, 2004, 9, 114-121.
- C. Capello, U. Fischer and K. Hungerbühler, What is a green solvent? A comprehensive framework for the environmental assessment of solvents, Green Chem., 2007, 9, 927-934.
- D. K. Leahy, J. L. Tucker, I. Mergelsberg, P. J. Dunn, M. E. Kopach and V. C. Purohit, Seven Important Elements for an Effective Green Chemistry Program: An IQ Consortium Perspective, Org. Process Res. Dev., 2013, 17, 1099-1109.